OSMOTIC COEFFICIENTS OF PHYSIOLOGICAL SOLUTES

n: number of particles that dissociated from the solute molecule.
M.W.: Molecular Weight.
f: osmotic coefficient of the solute

f is given for the concentrations these solutes are encountered in extracellular fluids of mammals.

You can use these values to calculate the osmolarity of physiological solutions.

Solute

n

M.W.

f

NaCl

2

58.5

0.93

KCl

2

74.6

0.92

HCl

2

36.6

0.95

NH4Cl

2

53.5

0.92

NaHCO3

2

84.0

0.96

NaNO3

2

85.0

0.90

KSCN

2

97.2

0.91

KH2PO4

2

136.0

0.87

CaCl2

3

111.0

0.86

MgCl2

3

95.2

0.89

Na2SO4

3

142.0

0.74

K2SO4

3

174.0

0.74

MgSO4

2

120.0

0.58

Glucose

1

180.0

1.01

Sucrose

1

342.0

1.02

Maltose

1

342.0

1.01

Lactose

1

342.0

1.01